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Title: | Pyrolytic lignin: a promising precursor for the green synthesis of fluorescent carbon nanoparticles. |
Authors: | APARICIO, R. R.![]() ![]() LIMA, G. G. de ![]() ![]() PERISSUTTI, G. E. ![]() ![]() BASSI, M. de J. ![]() ![]() JACUMAZO, J. ![]() ![]() SCHIAVON, M. A. ![]() ![]() ROMAN, L. S. ![]() ![]() MUNIZ, G. I. B. de ![]() ![]() MAGALHAES, W. L. E. ![]() ![]() CADEMARTORI, P. H. G. de ![]() ![]() |
Affiliation: | ROSINALDO RABELO APARICIO, UNIVERSIDADE FEDERAL DO PARANÁ; GABRIEL GOETTEN DE LIMA, PRISM RESEARCH INSTITUTE; GISELE ELIANE PERISSUTTI, CNPF; MAIARA DE JESUS BASSI, NANOSTRUCTURED DEVICES LABORATORY AT PHYSICS DEPARTMENT; JOSLAINE JACUMAZO, PHARMACEUTICAL SCIENCES GRADUATE PROGRAM; MARCO ANTÔNIO SCHIAVON, MATERIALS CHEMISTRY RESEARCH GROUP, DEPARTMENT OF NATURAL SCIENCES; LUCIMARA STOLZ ROMAN, MATERIALS SCIENCE AND ENGINEERING PROGRAM (PIPE), FEDERAL UNIVERSITY OF PARANÁ, POLYTECHNIC CENTER, CURITIBA 81531-990, BRAZIL; GRACIELA INES BOLZON DE MUNIZ, UNIVERSIDADE FEDERAL DO PARANÁ; WASHINGTON LUIZ ESTEVES MAGALHAES, CNPF; PEDRO HENRIQUE GONZALEZ DE CADEMARTORI, UNIVERSIDADE FEDERAL DO PARANÁ. |
Date Issued: | 2025 |
Citation: | ACS Omega, v. 10, n. 11, p. 11054-11062, 2025. |
Description: | This study presents a simple and cost-effective approach for synthesizing pyrolytic lignin-based carbon dots (CDPLs) via controlled thermal pyrolysis in water. To the best of our knowledge, this is the first time that pyrolytic lignin has been used as a precursor for carbon dots. The one-pot method produced blue/green fluorescent CDPLs with an average size of 34 nm and a negative surface charge of −10.4 mV. The characterization techniques revealed the optical properties and chemical composition of CDPLs, with a fluorescence quantum yield of 7.9%, which is comparable to those of lignin-derived carbon dots. The decay lifetime of CDPLs was in the nanosecond range, which is typical for carbon dots. This study demonstrates the potential of using pyrolytic lignin, a lignocellulosic byproduct, to produce carbon dots through a simple and reproducible method, contributing to the development of sustainable carbon-based nanomaterials. |
Thesagro: | Lignina Carbono |
NAL Thesaurus: | Carbon Pyrolysis Nanomaterials Lignin |
Keywords: | Nanopartícula Nanomateriais |
ISSN: | 2470-1343 |
Type of Material: | Artigo de periódico |
Access: | openAccess |
Appears in Collections: | Artigo em periódico indexado (CNPF)![]() ![]() |
Files in This Item:
File | Description | Size | Format | |
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ACS-Omega-Magalhaes-2025.pdf | 1.92 MB | Adobe PDF | ![]() View/Open |