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Título: EPR and DRIFT spectroscopic characterization of humic fractions during composting of sawdust and paper mill sludge.
Autor: MAIA, C. M. B. de F.
FUKAMACHI, C. R. B.
PICCOLO, A.
MANGRICH, A. S.
Afiliación: CLAUDIA MARIA BRANCO DE F MAIA, CNPF; CRISTIANE REGINA BUDZIAK FUKAMACHI, UFPR; ALESSANDRO PICCOLO, Università di Napoli Federico II; ANTONIO SÁLVIO MANGRICH, UFPR.
Año: 2012
Referencia: Pesquisa Florestal Brasileira, Colombo, v. 32, n. 70, p.117-122, abr./jun. 2012.
Descripción: The spectroscopic characteristics (DRIFT, UV-visible and EPR) of humic fractions were studied during composting of sawdust and paper mill sludge. Infrared spectroscopy reveals a compost rich in hydroxyl and alkyl groups and carboxylates and carbohydrates. The alkyl fraction is abundant in the humic acids and humin. The decreasing of the E4/E6 ratio during composting indicates an enhancement of the organic chains number, with conjugated double bonds. This decreasing would correspond to a reduction of the lignin content and/or formation of porphyrins. The EPR shows that humin presents the highest concentration of free radical and the lowest intensities of the Fe3+.
Palabras clave: Substância húmica
Humificação
UV-vis
Tipo de Material: Artigo de periódico
Acceso: openAccess
Aparece en las colecciones:Artigo em periódico indexado (CNPF)

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