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dc.contributor.authorMASCARENHAS, A. R. P.
dc.contributor.authorSCATOLINO, M. V.
dc.contributor.authorMEDEIROS, D. T.
dc.contributor.authorBATISTA, F. G.
dc.contributor.authorSETTER, C.
dc.contributor.authorMELO, R. R. de
dc.contributor.authorMARTINS, M. A.
dc.contributor.authorTONOLI, G. H. D.
dc.date.accessioned2024-09-12T18:54:31Z-
dc.date.available2024-09-12T18:54:31Z-
dc.date.created2024-09-12
dc.date.issued2024
dc.identifier.citationCERNE, v.30, e-103354, 2024.
dc.identifier.urihttp://www.alice.cnptia.embrapa.br/alice/handle/doc/1167344-
dc.descriptionABSTRACT Background: The production of cellulose microfibrils/nanofibrils (CMF/CNF) has attracted increasing attention in recent decades due to their excellent barrier, mechanical, and surface chemistry properties. However, large-scale industrial production of CMF/CNF has been a major challenge due to their high energy consumption, limiting their application. In this context, in recent years many studies have focused on developing pre-treatments designed to facilitate the fibrillation of CMF/CNF by reducing energy consumption during their production. This review highlights the latest advances in the use of silicates as chemical pre-treatments for CMF/CNF production, covering the main aspects related to the effects of chemical modification on the production and the properties of materials for application in biodegradable packaging. Results: Energy consumption reductions of up to 30% were achieved by pretreating cellulose pulps using silicates. In addition, the pre-treatments resulted in smaller CMF/CNF diameters and greater individualization of the nanofibrils. Studies evaluating the thermal stability, hydrophobicity, mechanical properties, and porosity of CMF/CNF pre-treated with silicates have reported promising results. The application of CMF/CNF pretreated with calcium and magnesium silicates in cardboard coating resulted in packaging with low water vapor permeability and high ductility. Conclusion: Silicates interact well with cellulose surfaces, making them a promising material for the chemical pre-treatment of CMF/CNF. Furthermore, the modification by silicates could be an interesting strategy for expanding the use of CMF/CNF in the development of new products.
dc.language.isoeng
dc.rightsopenAccess
dc.subjectBarrier properties
dc.subjectEnergy consumption
dc.subjectFiber modification
dc.subjectPaper coating
dc.titleSilicates as alternative pretreatment for cellulose pulp to obtain nanofibrils for application in biodegradable packaging: a technical review.
dc.typeArtigo de periódico
dc.format.extent21 - 11
riaa.ainfo.id1167344
riaa.ainfo.lastupdate2024-09-12
dc.identifier.doi10.1590/01047760202330013354
dc.contributor.institutionFEDERAL UNIVERSITY OF RONDÔNIA (UNIR); STATE UNIVERSITY OF AMAPÁ (UEAP); FEDERAL UNIVERSITY OF LAVRAS (UFLA); FEDERAL UNIVERSITY OF LAVRAS (UFLA); FEDERAL UNIVERSITY OF LAVRAS (UFLA); FEDERAL UNIVERSITY OF THE SEMIARID (UFERSA); MARIA ALICE MARTINS, CNPDIA; FEDERAL UNIVERSITY OF LAVRAS (UFLA).
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