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Título: Pyrolytic lignin: a promising precursor for the green synthesis of fluorescent carbon nanoparticles.
Autor: APARICIO, R. R.
LIMA, G. G. de
PERISSUTTI, G. E.
BASSI, M. de J.
JACUMAZO, J.
SCHIAVON, M. A.
ROMAN, L. S.
MUNIZ, G. I. B. de
MAGALHAES, W. L. E.
CADEMARTORI, P. H. G. de
Afiliación: ROSINALDO RABELO APARICIO, UNIVERSIDADE FEDERAL DO PARANÁ; GABRIEL GOETTEN DE LIMA, PRISM RESEARCH INSTITUTE; GISELE ELIANE PERISSUTTI, CNPF; MAIARA DE JESUS BASSI, NANOSTRUCTURED DEVICES LABORATORY AT PHYSICS DEPARTMENT; JOSLAINE JACUMAZO, PHARMACEUTICAL SCIENCES GRADUATE PROGRAM; MARCO ANTÔNIO SCHIAVON, MATERIALS CHEMISTRY RESEARCH GROUP, DEPARTMENT OF NATURAL SCIENCES; LUCIMARA STOLZ ROMAN, MATERIALS SCIENCE AND ENGINEERING PROGRAM (PIPE), FEDERAL UNIVERSITY OF PARANÁ, POLYTECHNIC CENTER, CURITIBA 81531-990, BRAZIL; GRACIELA INES BOLZON DE MUNIZ, UNIVERSIDADE FEDERAL DO PARANÁ; WASHINGTON LUIZ ESTEVES MAGALHAES, CNPF; PEDRO HENRIQUE GONZALEZ DE CADEMARTORI, UNIVERSIDADE FEDERAL DO PARANÁ.
Año: 2025
Referencia: ACS Omega, v. 10, n. 11, p. 11054-11062, 2025.
Descripción: This study presents a simple and cost-effective approach for synthesizing pyrolytic lignin-based carbon dots (CDPLs) via controlled thermal pyrolysis in water. To the best of our knowledge, this is the first time that pyrolytic lignin has been used as a precursor for carbon dots. The one-pot method produced blue/green fluorescent CDPLs with an average size of 34 nm and a negative surface charge of −10.4 mV. The characterization techniques revealed the optical properties and chemical composition of CDPLs, with a fluorescence quantum yield of 7.9%, which is comparable to those of lignin-derived carbon dots. The decay lifetime of CDPLs was in the nanosecond range, which is typical for carbon dots. This study demonstrates the potential of using pyrolytic lignin, a lignocellulosic byproduct, to produce carbon dots through a simple and reproducible method, contributing to the development of sustainable carbon-based nanomaterials.
Thesagro: Lignina
Carbono
NAL Thesaurus: Carbon
Pyrolysis
Nanomaterials
Lignin
Palabras clave: Nanopartícula
Nanomateriais
ISSN: 2470-1343
Tipo de Material: Artigo de periódico
Acceso: openAccess
Aparece en las colecciones:Artigo em periódico indexado (CNPF)

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