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dc.contributor.authorFERREIRA, M. L.
dc.contributor.authorMODA, T.
dc.contributor.authorBROCKSOM, U.
dc.contributor.authorBROCKSOM, T. J.
dc.date.accessioned2025-06-17T19:47:35Z-
dc.date.available2025-06-17T19:47:35Z-
dc.date.created2004-10-27
dc.date.issued2003
dc.identifier.citationIn: BRAZILIAN MEETING ON ORGANIC SYNTHESIS, 10., 2003, São Pedro. [Abstracts...]. Campinas: Unicamp, 2003.
dc.identifier.urihttp://www.alice.cnptia.embrapa.br/alice/handle/doc/309712-
dc.descriptionWe have been investigating the synthesis of (+)-Sarcophytin o (3) and correlated compounds, and also studying their possible phytotoxic activity. For the synthesis of the tetracyclic nucleus of the C-1-epimer of (+)-3, we chose the halocyclization reaction (NBS in THF/H>20) of Diels-Alder (o) cycloadduct (+)-1, producing compound (+)-2 in 81% yield. Thus (+)-2 can now be obtained in six steps from the cheap chiron (R)-(+)-pulegone in 24% overall yield.
dc.language.isoeng
dc.rightsopenAccess
dc.subjectSarcophytin
dc.subjectDiels-Alder
dc.subjectPhytotoxic
dc.titleSynthesis of the tetracyclic nucleus of epi-Sarcophytin, and evaluation of its activity.
dc.typeResumo em anais e proceedings
riaa.ainfo.id309712
riaa.ainfo.lastupdate2025-06-17
dc.contributor.institutionMARIA LUCIA FERREIRA, CNPF.
Aparece en las colecciones:Resumo em anais de congresso (CNPF)

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