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Título: | EPR and DRIFT spectroscopic characterization of humic fractions during composting of sawdust and paper mill sludge. |
Autor: | MAIA, C. M. B. de F.![]() ![]() FUKAMACHI, C. R. B. ![]() ![]() PICCOLO, A. ![]() ![]() MANGRICH, A. S. ![]() ![]() |
Afiliación: | CLAUDIA MARIA BRANCO DE F MAIA, CNPF; CRISTIANE REGINA BUDZIAK FUKAMACHI, UFPR; ALESSANDRO PICCOLO, Università di Napoli Federico II; ANTONIO SÁLVIO MANGRICH, UFPR. |
Año: | 2012 |
Referencia: | Pesquisa Florestal Brasileira, Colombo, v. 32, n. 70, p.117-122, abr./jun. 2012. |
Descripción: | The spectroscopic characteristics (DRIFT, UV-visible and EPR) of humic fractions were studied during composting of sawdust and paper mill sludge. Infrared spectroscopy reveals a compost rich in hydroxyl and alkyl groups and carboxylates and carbohydrates. The alkyl fraction is abundant in the humic acids and humin. The decreasing of the E4/E6 ratio during composting indicates an enhancement of the organic chains number, with conjugated double bonds. This decreasing would correspond to a reduction of the lignin content and/or formation of porphyrins. The EPR shows that humin presents the highest concentration of free radical and the lowest intensities of the Fe3+. |
Palabras clave: | Substância húmica Humificação UV-vis |
Tipo de Material: | Artigo de periódico |
Acceso: | openAccess |
Aparece en las colecciones: | Artigo em periódico indexado (CNPF)![]() ![]() |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
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2012APIMaiaEPRandDRIFT.pdf | 286.75 kB | Adobe PDF | ![]() Visualizar/Abrir |